Buying the Orange Box from Gamestop.com

I have a gamestop gift card for $25 dollars laying in front of me, and I was wondering if downloading the Orange Box from their site has the games register under Steam.
I know that two of the games in the Orange Box are already F2P, but I do not have a Credit Card and would still like to have a regular steam account rather than a limited one (Also Half Life 2 is pretty damn awesome).
So my questions are, does downloading the Orange Box from gamestop.com get me the games on Steam, and would that give me a Premium TF2 account (maybe I could get into it more)

 

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